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Chemostratigraphy of some key European Frasnian-Famennian boundary sections (Germany, Poland, France

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Inhaltsverzeichnis
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About this book

Figure 1. Diagram showing the main ‘events’ along the late D
Page 4
Figure 2. Paleogeographic reconstruction of the Upper Devoni
Page 9
Table 1. Synthetic table presenting the arguments advanced
Page 10
Table 2. Synthetic table presenting the arguments advanced i
Page 11
Figure 3. Lithologs and samples position of the investigated
Page 13
Figure 4. Location map of the Kowala section in Poland (modi
Page 14
Page 14
Figure 5. Location of the Frasnian/Famennian boundary in the
Page 14
Figure 6. Location map of the Büdesheimer Bach core (modifie
Page 15
Figure 7. 4 meters core box of Büdesheimer Bach stored in th
Page 16
Figure 8. Location map of the Steinbruch Schmidt section (mo
Page 17
Figure 9. Location of the Frasnian/Famennian boundary and th
Page 17
Figure 10. The lower Kellwasser Horizon with the position of
Page 18
Figure 11. Location map of the Devonian of the Montagne Noir
Page 19
Figure 12. Location map of Coumiac (modified after House et
Page 20
Figure 13. Location of the Frasnian/Famennian boundary and t
Page 20
Figure 14. Location of the Lower Kellwasser Horizon (Bank 24
Page 21
Figure 15. Location map of La Serre trench C (modified after
Page 21
Figure 16. Location of the Frasnian/Famennian boundary in th
Page 22
Table 3. Characteristics of the ED-XRF trace elements result
Page 24
Table 4. Characteristics of the WD-XRF major and trace elem
Page 25
Figure 17. Distribution of the Al2O3 (%) contents along the
Page 29
Figure 18. Distribution of the quartz contents (Integrated i
Page 30
Figure 19. Distribution of the Ti/Al ratios along the sectio
Page 31
Figure 20. Distribution of the Si/Al ratios along the sectio
Page 31
Figure 21. Distribution of the Na/K ratios along the section
Page 32
Figure 22. Distribution of the K/Fe+Mg ratios along the sect
Page 32
Figure 23. Distribution of the Corg (%) contents along the s
Page 34
Figure 24. Distribution of the P2O5 content in excess (P2O5*
Page 36
Figure 25. Distribution of the Ba content in excess (Ba*) al
Page 36
Figure 26. Barite (left) and FluoroApatite at the F/F bounda
Page 37
Figure 27. Distribution of the V/Cr ratios along the section
Page 39
Figure 28. Distribution of the Ni/Co ratios along the sectio
Page 39
Figure 29. Framboidal pyrite in the UKWH of the Büdesheimer
Page 40
Figure 30. Framboidal pyrite in the LKWH of the Büdesheimer
Page 40
Figure 31. Distribution of the Al/(Al+Fe+Mn) ratios along th
Page 43
Figure 32. Distribution of the Cr/Al ratios along the sectio
Page 44
Figure 33. Distribution of the Mn/Al ratios along the sectio
Page 44
Figure 34. Distribution of the S contents (wt.%) along the s
Page 45
Figure 35. Framboidal pyrite at the F/F boundary in the bank
Page 45
Figure 36. Iron oxide (with Si) in the bank 13a of the La Se
Page 45
Figure 37. Distribution of the Zr/Al2O3 (*100) ratios along
Page 47
Figure 38. Distribution of the Mg/Al ratios along the sectio
Page 47
Figure 39. Factor loadings of the different standardized pro
Page 50
Figure 40. Factor loadings of the different standardized pr
Page 51
Table 5. Summarized observations made in the Kellwasser Hor
Page 52
Figure 41. Flow-chart illustrating the possible links betwee
Page 59
Figure 42. Representation of the overall process of sediment
Page 61
Table 6. Example of the ICP-MS trace elements results charac
Page 68
Figure 43. Crossplot of Corg (%) content vs. S content (%) i
Page 71
Figure 44. Crossplot of As content (ppm) vs. S content (%) u
Page 71
Figure 45. Crossplot of DOP vs. reactive iron content (ppm)
Page 72
Figure 46. Example of cubic pyrite crystals present in the L
Page 73
Figure 47. Tree diagram of the reactive elements fraction by
Page 74
Figure 48. Crossplot of DOP vs. U reactive/Th reactice ratio
Page 76
Figure 49. Tree diagram of the reactive elements fraction an
Page 77
Figure 50. Tree diagram of the trace element contents in pyr
Page 78
Figure 51. Crossplot of DOP vs. Ni content in pyrite.
Page 79
Figure 52. Tree diagram of the trace element contents in pyr
Page 80
Figure 53. Crossplot of the pyrite morphology vs. Ni content
Page 80
Figure 54. Distribution of the Mn, As, U in pyrite along th
Page 81
Figure 55. Crossplot of U content in pyrite vs. morphology a
Page 81
Figure 56. Tree diagram of the trace element contents in py
Page 84
Figure 57. Crossplot of the As content in pyrite (ppm) vs.
Page 85
Figure 58. Crossplot of the Corg content (%) and DOP vs. Cd
Page 85
Figure 59. Crossplot of P2O5* and Ba* vs. As content in pyr
Page 85
Figure 60. Crossplot of P2O5* and Ba* vs. U content in pyr
Page 86
Figure 61. Crossplot of Ni content in pyrite (ppm) vs. DOP
Page 86
Figure 62. Crossplot of the ankerite integrated intensity (
Page 89
Figure 63. Crossplot of the DOP vs. DTMP of Ni and Co inclu
Page 89
Figure 64. Model showing the parameters involved in the DTMP
Page 89
Figure 65. Model showing the parameters involved in the DTM
Page 90
Figure 66. Model showing the parameters involved in the DTMP
Page 90
Figure 67. Distribution of the DOP, the δ34Spyrite (‰ V-CDT)
Page 92
Figure 68. Crossplot of δ34Spyrite (‰ V-CDT) vs. Corg (%) an
Page 92
Table 7. Results of the synchrotron μ-XRF analysis on differ
Page 93
Table 8. Results of the Kowala section analysis.
Page 119
Table 9. Results of the Büdesheimer Bach section analysis.
Page 122
Table 10. Results of the Steinbruch Schmidt section analysis
Page 126
Table 11. Results of the Coumiac (Stratotype) section analys
Page 127
Table 12. Results of the La Serre trench C section analysis.
Page 128

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Abstract: This study aimed to put constraints on regional and/or global environmental changes, which took place during the Frasnian-Famennian transition by using a geochemical multiproxy approach. The investigation of several key European Frasnian-Famennian boundary sections brings new geochemical evidences which emphasize the role of tectono-magmatic processes, like volcanism, hydrothermalism and major tectonic movements in the development of the particularities of the Kellwasser Horizons deposited close to the southern shores of Laurussia and the northern parts of Gondwana.